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"If I had to get a new Ph.D. now, I'd get it in polymer engineering - the manipulation of matter."
- Bart Kosko

Dud  
  Mysterious silvery spheres.  

"Dud", Locke said. DuBrose had not thought the pilot had noticed his movement.

“One of the domes, that’s all,” Cameron said, settling back. But DuBrose didn’t stop staring at the silvery, tattered thing on the hillside.

It was a hemisphere, a hundred feet in diameter, and there were seventy-four of them scattered over America, all exactly alike. DuBrose could not remember when they had been perfectly opaque, mirror silvery shells ; he had been eight years old when they had appeared out of nowhere, all at once, cryptic with their secret that had never been solved. No one had been able to get into them, and nothing tangible had ever come out. Seventy-four shining hemispheres had come from somewhere, causing a near-panic. Another secret weapon of the enemy...

Then the unbroken smoothness of the domes began to be marred. Striae made networks across the polished substance that wasn't matter. And the webs broadened, as though quicksilver were flaking from the back of a mirror, until the shells were tattered and split. It was impossible to see inside them, but there was nothing inside — simply bare ground.

Nevertheless no one had been able to get into a dome. The force, whatever it was, remained constant; something like solid energy made an impassable barrier to solids.

Long since the public, continuing to think the enigmas a secret weapon that had failed, had named them Duds. The title stuck.

Technovelgy from The Fairy Chessmen, by Lewis Padgett.
Published by Astounding Science Fiction in 1946
Additional resources -

Compare to the bobbles from The Peace War by Vernor Vinge.

For the hemispherical protection of cities, compare to the wall in the air from Rondah, or Thirty-Three Years in a Star (1887) by Florence Carpenter Dieudonné, the lanson screen from The Lanson Screen (1936) by Leo Zagat, the spindizzy from Cities in Flight (1957) by James Blish and the Langston Field from The Mote in God's Eye (1974) by Larry Niven (w/J. Pournelle).

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Additional resources:
  More Ideas and Technology from The Fairy Chessmen
  More Ideas and Technology by Lewis Padgett
  Tech news articles related to The Fairy Chessmen
  Tech news articles related to works by Lewis Padgett

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