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"Science fiction is really sociological studies of the future, things that the writer believes are going to happen by putting two and two together."
- Ray Bradbury

Black Smoke  
  A smoke or vapor dispensed in canisters.  

Unable from his window to learn what was happening, my brother went down and out into the street, just as the sky between the parapets of the houses grew pink with the early dawn. The flying people on foot and in vehicles grew more numerous every moment. "Black Smoke!" he heard people crying, and again "Black Smoke!" The contagion of such a unanimous fear was inevitable. As my brother hesitated on the door-step, he saw another news vender approaching, and got a paper forthwith. The man was running away with the rest, and selling his papers for a shilling each as he ran--a grotesque mingling of profit and panic.

And from this paper my brother read that catastrophic dispatch of the Commander-in-Chief:

"The Martians are able to discharge enormous clouds of a black and poisonous vapour by means of rockets. They have smothered our batteries, destroyed Richmond, Kingston, and Wimbledon, and are advancing slowly towards London, destroying everything on the way. It is impossible to stop them. There is no safety from the Black Smoke but in instant flight."

That was all, but it was enough. The whole population of the great six-million city was stirring, slipping, running; presently it would be pouring en masse northward.

"Black Smoke!" the voices cried. "Fire!"

From The War of the Worlds, by H.G. Wells.
Published by Unknown in 1898
Additional resources -

This excerpt deals with the composition of the Black Smoke:

Neither is the composition of the Black Smoke known, which the Martians used with such deadly effect, and the generator of the Heat-Rays remains a puzzle. The terrible disasters at the Ealing and South Kensington laboratories have disinclined analysts for further investigations upon the latter. Spectrum analysis of the black powder points unmistakably to the presence of an unknown element with a brilliant group of three lines in the green, and it is possible that it combines with argon to form a compound which acts at once with deadly effect upon some constituent in the blood. But such unproven speculations will scarcely be of interest to the general reader, to whom this story is addressed. None of the brown scum that drifted down the Thames after the destruction of Shepperton was examined at the time, and now none is forthcoming.

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Additional resources:
  More Ideas and Technology from The War of the Worlds
  More Ideas and Technology by H.G. Wells
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