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"It's hard to tell stories about critters that are not human. John W. Campbell tried it, in "Twilight," and everybody says it's a wonderful story, and nobody ever reads it twice."
- Jerry Pournelle

Syn-Cof  
  Synthetic coffee.  

The waitress came for Jim's order.

"Perkin's Syn-Cof," he murmured absently.

From Cantata 140, by Philip K. Dick.
Published by Fantasy and Science Fiction in 1964
Additional resources -

Here's another bit:

"Let's get something warm to drink," Pat said."...we can fix some synthetic, non-toxic coffee inside..."

Sipping, Sal Heim said "Tastes good."

"Yes," Jim Briskin agreed. In fact, the cup of hot coffee, synthetic and non-toxic as it had to be (only low-stratum, dorm-housed Cols drank the genuine thing) was exactly what he needed. It made him feel a lot better.

Don't miss the entry for coffiest from the sardonic 1952 Pohl/Kornbluth novel The Space Merchants.

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Additional resources:
  More Ideas and Technology from Cantata 140
  More Ideas and Technology by Philip K. Dick
  Tech news articles related to Cantata 140
  Tech news articles related to works by Philip K. Dick

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