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"Generally, the human race avoids doing anything radical until forced into it."
- Frederik Pohl

Thought Shield  
  A device that removes intrusive thoughts from your mind.  

As far as I know, the first use of the phrase "thought shield" in science fiction.

“There is a very delicate micrometer screw near the base of the protuberance.” We examined it more closely. Sure enough it was there. He continued. “Each half turn of that screw shifts the period of vibration by half a wave length. So that is merely a matter of experimental individual adj ustment for each wearer.”

“But how can you tell when it is properly set,” I asked.

“Put it on, and I’ll show you,” the earthman from Neptune replied. I did so, the flexible band encircled my forehead, with the knob in front, the electrodes in the rear.

“Now turn the micrometer screw until you notice something unusual.”

My clumsy fingers found the little mechanism, twisted it slowly. Nothing happened. I was beginning to fear it was some Neptunian jest, when suddenly my usually halting thought processes clarified. Instead of vague chaotic tags and shreds of thought flitting through my mind, consecutive ideas came to me, clear cut, sharp edged, crystalline.

I stopped short with an exclamation of surprise. Never before had I felt my brain so keen, so brilliant.

“Ah, I can see you have found the proper vibration series,” said Arkon, who had heen watching me closely.

“What is it, how did you know when to stop?” clamored Sid, bursting with curiosity.

I described my sensations, Arkon nodding his head the while. “That is so. Your thought vibrations are now completely shielded from the fest of the world, you see, by forming a wall of neutralization, the waves of thought pressing behind are thrown back upon themselves, and they reinforce and amplify so that the sensations, the ideas they represent, are made more vigorous, more intense.”

“There is only one thought-shield,” came the grave voice of Arkon.

“Then I’m elected,” said Sid, and he tried to grab the circlet off my head. I ducked just in time.

“Not a chance. I’m a reporter, don’t forget. I have a natural nose for news, for prying into things."

Technovelgy from Back to 20,000 A.D., by Nat Schachner (w. AL Zagat).
Published by Wonder Stories in 1931
Additional resources -

Compare to the Tin Foil Hat (Tin Pulpit) from The Tissue-Culture King (1927) by Julian Huxley, which is apparently the original story from which the "tin foil hat" idea is taken.

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Additional resources:
  More Ideas and Technology from Back to 20,000 A.D.
  More Ideas and Technology by Nat Schachner (w. AL Zagat)
  Tech news articles related to Back to 20,000 A.D.
  Tech news articles related to works by Nat Schachner (w. AL Zagat)

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