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"I was involved in a cloning project. .. to send me into outer space along with a lot of other people. Not the whole me - just a hair from my head, while I still had some. I would thus pop up in another galaxy in the distant future."
- Arthur C. Clarke

Jetta Tube  
  Spray causes immediately a trance-like state where a person’s body becomes rigid.  

THE steel door clicked open. A man stood in the entrance, flanked by two guards armed with jetta tubes. These were the weapons worn by the dictator’s police; the fine spray that could be shot from them produced instant catalepsy, terminating in death, unless a secret antidote was given.
Technovelgy from Revolt on Inferno, by Victor Rousseau.
Published by Miracle Science and Fantasy Stories in 1931
Additional resources -

Handy stuff, easily concealed:

He fingered the miniature jetta-tube through the cloth of his pocket-flap. The atomized spray acted instantaneously, but only upon contact with human flesh; inhaled, it was harmless; one molecule upon Donald’s face would throw him into immediate catalepsy. Armed with a single tube, Danvril was invincible against the whole shipload of conspirators.

Compare to the cellphone tranquilizing spray from The Age of The Pussyfoot (1966) by Frederik Pohl.

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Additional resources:
  More Ideas and Technology from Revolt on Inferno
  More Ideas and Technology by Victor Rousseau
  Tech news articles related to Revolt on Inferno
  Tech news articles related to works by Victor Rousseau

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