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"In science fiction one can say a great many things that are unpalatable, … because it's expressed as science fiction you can slip it past their defenses."
- Frederik Pohl

Plexiskin  
  A means of disguise.  

His own face is too well known for him to have investigated personally, and he's not enough of an actor to get away with using a plexiskin mask...
Technovelgy from A Spaceship Named McGuire, by Gordon Randall Garrett.
Published by Analog in 1961
Additional resources -

Compare to uniflesh from The Dosadi Experiment (1977) by Frank Herbert and the moon moth mask from The Moon Moth (1976) by Jack Vance.

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Additional resources:
  More Ideas and Technology from A Spaceship Named McGuire
  More Ideas and Technology by Gordon Randall Garrett
  Tech news articles related to A Spaceship Named McGuire
  Tech news articles related to works by Gordon Randall Garrett

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I might also be thinking of K-9 from Doctor Who.

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