Self-Healing Polymer Autonomous Material System

Everywhere you look, exposed surfaces are cracking. Asphalt streets are cracked, building facades are cracked, the paint on your house is cracked and flaking - the list is endless.

What if you could have a surface that repaired itself?

After all, you have a surface that heals itself - your skin. When you get a cut or a scratch, living cells deep in the living layers of your skin replace the old ones on the surface.


(Self-healing Polymer)
Left: Cross section of the self-healing surface showing that cracks, which initiate at the surface, propagate towards the microchannel openings at the interface (scale bar=0.5 mm). Right: Optical image of the self-healing structure after cracks are formed in the coating, revealing the presence of excess healing fluid on the coating surface (scale bar=5 mm)

A team of researchers at the University of Illinois have used a technique create a polymer-based system that heals itself. An epoxy-resin base is infused with a network of interconnected channels about 200 microns in diameter. The channels are filled with low viscosity monomeric dicyclopentadiene - the healing agent. This "vascularized" substrate has a solid epoxy layer deposited on top of it. A catalyst is incorporated in this solid coating.

When the coating layer is damaged, healing agent wicks from the channels through capillary action.

"Once in the crack plane the healing agent interacts with the catalyst particles in the coating to initiate polymerisation, rebonding the crack faces autonomically. After a sufficient time period the cracks are healed and the structural integrity of the coating restored. As cracks reopen under subsequent loading the healing cycle is repeated."

The idea of a "self-healing" surface is part of a larger set of ideas called "autonomous materials systems." The intent is to develop materials that can respond to their environment without additional attention from human beings. This idea has wide application not only here on Earth, but in space as well.

This week, a torn heat-resistant blanket must be repaired on the space shuttle Atlantis before it can return from orbit. The tiles on the shuttles also require inspection. What if it was possible for shuttles to have "skin" that repaired itself when cracked or damaged?

Researchers are busy creating futuristic materials; see also

Namib Desert Beetle-Based Moisture Collectors
MIT researchers, inspired by the beetle, have created a material that can capture and control tiny amounts of water.

Shape-Shifting Polymers
See the shape-shifting polymers do their thing in the video.

Arachnid Adhesion: The Sticky Feet Of Spiders
Scientists from Germany and Switzerland used a scanning electron microscope to find out how they do it - and how humans might make sticky things stickier.

There is an early direct reference to this idea in science fiction. In his 1962 story The Thousand Dreams of Stellavista, J.G. Ballard refers to a material called plastex, which allows for self-healing buildings.

See also this story on an attempt to create an earthquake-proof Nanotech Self-Healing House in Greece. Read more about the self-healing polymer. Thanks to Adi for the tip on this story.

Scroll down for more stories in the same category. (Story submitted 6/13/2007)

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