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"I realized there was a heavy-duty change coming in biology, and I could write a really compelling novel about catastrophic evolution, punctuated equilibrium."
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Although Brin did not coin the word "unobtainium" he might well be the first user of it in science fiction. See the discussion below.
The best guesses as to the origin of the word place it in the field of aerospace, which has been pushing the envelope in the field of materials science for at least a century.
As reported in the Marshall Evening Chronicle (Marshall, Michigan) on February 27, 1956:
However, it can be found even earlier in a 1930 German work "Dechema-Monographium Vol 39 page 12 link:
[Google Translate: ...Weight equal to zero. An American has jokingly called this material once the element "Unobtainium".]
The earliest reference to something like this (that is, a humorous name for a material that does not exist) is as far as I know "Bolognium" from Transactions of Amer Soc for Steel Treating, by Edgar Bain, in 1926.
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Science Fiction
Timeline
Biohybrid Robots Made Of Living And Synthetic Materials
'If the biological robots were not living creatures, they were certainly very good imitations.'
Poul Anderson's 'Brain Wave'
"Everybody and his dog, it seemed, wanted to live out in the country; transportation and communication were no longer isolating factors."
AI Note-Taking From Google Meet
'... the new typewriter that could be talked to, and which transposed the spoken sound into typed words.'
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'... underneath they consisted of networks of cooling tubes against the skin.'
Waymo Cars Shout At Each Other, Autonomously
'My cars talk to one another. I have no doubt about it...'
Seeing Faces On Grains Of Sand (AI Pareidolia)
'... the imprint of her image on the telephoto cell.'
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