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"If you don't care about science enough to be interested in it on its own, you shouldn't try to write hard science fiction."
- Frederik Pohl

Super-Weapon  
  A generic term for an advanced destructive device or technology.  

As far as I know, this is the first instance of this handy phrase.

Neither side dares attack the other; each is waiting for the development of some super-weapon which will give it the overwhelming advantage necessary to insure victory upon a field of action so far from home.
Technovelgy from Robot Nemesis, by E.E. 'Doc' Smith.
Published by Thrilling Wonder Stories in 1939
Additional resources -

Take a look at the general category page for weapon for dozens of examples! Also, please comment with your own favorites.

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Additional resources:
  More Ideas and Technology from Robot Nemesis
  More Ideas and Technology by E.E. 'Doc' Smith
  Tech news articles related to Robot Nemesis
  Tech news articles related to works by E.E. 'Doc' Smith

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