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"Does it open a new horizon for my thinking? Does it lead me to think new kinds of thoughts, that I would not otherwise perhaps have thought at all? These qualities are what [make] science fiction ...unique."
- Frederik Pohl

Vacuum Armor  
  An armor-plated space suit.  

Very early reference to the idea of a special suit that was proof against the vacuum of space.

Nothing could be seen of the person of the stranger, since he was encased in vacuum armor, but it was plainly evident that he was very short and immensely broad and thick.
Technovelgy from Skylark Three, by E.E. 'Doc' Smith.
Published by Amazing Stories in 1930
Additional resources -

Compare to space-armor from Revolt of the Star Men (1932) by Raymond Z Gallun, Osprey space armor from Salvage in Space (1933) by Jack Williamson, lightweight space armor from Hotel Cosmos (1938) by Raymond Z. Gallun, Dirigible Space Armor (Working Space Suits) from Collision Orbit (1941) by Jack Williamson, and space armor from Cities in Flight (1957) by James Blish.

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Additional resources:
  More Ideas and Technology from Skylark Three
  More Ideas and Technology by E.E. 'Doc' Smith
  Tech news articles related to Skylark Three
  Tech news articles related to works by E.E. 'Doc' Smith

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