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Self-Assembling Nanoparticles Move Like Tiny Gears
Researchers funded by the US Air Force have been working with silver lattices—alternating layers of crystalline silver nanoparticle clusters and an organic buffer material. The researchers noticed that when the materials self-assembled, there was a mechanical action; the particle structures rotated like very tiny gear.
(Pressure moves molecular gears video)
"As we squeeze on this material, it gets softer and softer and suddenly experiences a dramatic change," said Uzi Landman, of the Georgia Institute of Technology. "When we look at the orientation of the microscopic structure of the crystal in the region of this transition, we see that something very unusual happens. The structures start to rotate with respect to one another, creating a molecular machine with some of the smallest moving elements ever observed." In each layer of the superlattice, those gears move in opposite directions to each other, and when pressure is taken again removed from the material, researchers found that these gears return to their original positions.The gear motion is the result of the particular self-assembly process of the material. "Self-assembly" here is maybe not all that you expect; the material is not some from-scratch autonomous creation. Rather, the material is begun as a solution of molecules with a predisposition for bonding with each other at particular angles via hydrogen atoms/hydrogen bonds.
Science fiction author Philip K. Dick is arguably the first person to describe self-assembling nanomachines. In his 1955 short story Autofac, Dick described an automated factory that had the capacity to reproduce itself by shooting tiny pellets full of nanomachines into the distance:
The cylinder had split. At first he couldn't tell if it had been the impact or deliberate internal mechanisms at work. From the rent, an ooze of metal bits was sliding. Squatting down, O'Neill examined them.The bits were in motion. Microscopic machinery, smaller than ants, smaller than pins, working energetically, purposefully - constructing something that looked like a tiny rectangle of steel.
"They're building," O'Neill said, awed...
(Read more about Philip K. Dick's autofac)
I'd also add a reference to a more structured version of this idea, the Robot Cells (Crystal-Shaped Modules) from 1987 work by Michael P. Kube-McDowell.
From Vice and Hydrogen-bonded structure and mechanical chiral response of a silver nanoparticle superlattice via Frolix_8 Hydrogen-bonded structure and mechanical chiral response of a silver nanoparticle superlattice
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